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The mechanical strength of polysilicon films : Part 1. The influence of fabrication governed surface conditions

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Title The mechanical strength of polysilicon films : Part 1. The influence of fabrication governed surface conditions
 
Creator Chasiotis, Ioannis
Knauss, Wolfgang G.
 
Subject Caltech Library Services
 
Description In an effort to explain the considerable variations in measured mechanical strength of polysilicon films doped with phosphorous for use in MEMS applications, the influence of the specimen manufacturing processes on the mechanical properties has been examined in connection with varying exposure to 49% hydrofluoric acid (HF). It was found that surface roughness as characterized by groove formation along grain boundaries depends on the HF release time. Surface undulations and crevasses related to grain structure result thus in reduced fracture strength and, in addition, induce errors into the determination of the effective elastic modulus - especially when the latter is determined from flexure configurations. Extensive exposure to HF results in pervasive material degradation, as evidenced by a transition from transgranular to intergranular fracture, and a correspondingly precipitous drop of the film strength with attendant increase in grain boundary material removal. Short times of exposure to HF can result in delamination of a thin surface layer, which is suffcient to initiate an "early" failure. Longer exposure allows HF permeation into the intergranular domains, degrading the body of the material significantly. On the other hand, tests on material from a different source that has undergone different doping and post-processing demonstrated a suppression of this degradation resulting in film strengths that are higher by a factor of two or more. Thus, consideration of additional influences of doping and electro-chemical phenomena during the HF wet release, in association with silicon-metal contacts, is necessary.
 
Publisher Elsevier
 
Date 2003-08
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://authors.library.caltech.edu/22/1/CHAjmps03a.pdf
Chasiotis, Ioannis and Knauss, Wolfgang G. (2003) The mechanical strength of polysilicon films : Part 1. The influence of fabrication governed surface conditions. Journal of the Mechanics and Physics of Solids, 51 (8). pp. 1533-1550. ISSN 0022-5096. http://resolver.caltech.edu/CaltechAUTHORS:CHAjmps03a <http://resolver.caltech.edu/CaltechAUTHORS:CHAjmps03a>
 
Relation http://resolver.caltech.edu/CaltechAUTHORS:CHAjmps03a
http://authors.library.caltech.edu/22/