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Sonochemical Degradation of Pollutants

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Title Sonochemical Degradation of Pollutants
 
Creator Destaillats, Hugo
Hoffmann, Michael R.
Wallace, Henry C.
 
Description The term sonochemistry describes all chemical processes in which ultrasound irradiation is involved. The interaction of an acoustical field with the irradiated fluid provides new reaction pathways and alters existing chemical processes in the system, usually yielding an enhancement of reaction rates. A distinction should be pointed out between the effects of ultrasound in homogeneous and in heterogeneous media. In the first case, sonochemical reactions are related to new chemical species produced during acoustical cavitation, whereas the enhancement of heterogeneous reactions can also be related to mechanical effects induced in the fluid system by sonication. These effects include an increase in the surface area between the reactants, a faster renovation of catalyst surfaces, and accelerated dissolution and mixing. Although this chapter focuses only on the uses of ultrasound related to the degradation of organic pollutants, we should mention that many other sonochemical processes exist, such as organic and organometallic synthesis, and polymer synthesis and modifications.
 
Publisher Marcel Dekker
 
Contributor Tarr, Mathew A.
 
Date 2003
 
Type Book Section
PeerReviewed
 
Relation http://resolver.caltech.edu/CaltechAUTHORS:20150821-094827159
http://authors.library.caltech.edu/59807/
 
Identifier Destaillats, Hugo and Hoffmann, Michael R. and Wallace, Henry C. (2003) Sonochemical Degradation of Pollutants. In: Chemical Degradation Methods for Wastes and Pollutants. Environmental Science and Pollution Control Series. No.26. Marcel Dekker , New York, NY, pp. 201-233. ISBN 0-8247-4307-5 http://resolver.caltech.edu/CaltechAUTHORS:20150821-094827159 <http://resolver.caltech.edu/CaltechAUTHORS:20150821-094827159>